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- W2062716298 abstract "A reaction of pyrrole and copper(II) perchlorate in acetonitrile yielded highly conducting polypyrrole, [(C4H3N)(C104)x·yH2O]n: a polymer with x = 0.35 and y = 0.25 exhibited a conductivity of 60 S cm−1 and a very low activation energy of 0.011 eV. The e.s.r. spectrum was asymmetric and the g value was 2.0017 that was slightly smaller than the free electron value. These are suggestive of a Dysonian line due to a metal-like charge transport along polymer chains. Materials treated with NH4OH solution showed an infrared spectrum characteristic of polypyrrole." @default.
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- W2062716298 date "1989-01-01" @default.
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- W2062716298 title "Chemical synthesis of highly conducting polypyrrole by the use of copper(II) perchlorate as an oxidant" @default.
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- W2062716298 doi "https://doi.org/10.1016/0379-6779(89)90500-6" @default.
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