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- W2062736834 abstract "The collision-induced absorption of the symmetric vibration of CO2 has been observed in the pure gas at densities from 20.0 to 40.0 amagat and at temperatures of 273, 298, and 323 K using infrared techniques. From the integrated intensities of the bands and using the (exp −4) model of van Kranendonk, it is possible to deduce a value for the first derivative of the quadrupole moment with respect to the vibrational coordinate. For CO2 the contribution from quadrupole distortion to the binary absorption coefficient is reported for several temperatures. The (exp −4) model of van Kranendonk is used to calculate the binary absorption coefficients for the fundamental vibrational bands of N2 and O2 at temperatures from 70 to 340 K. The parameters λ and p/σ describing the magnitude and range of the short-range collision-induced dipole moments were determined using the known experimental absorption coefficients. The contributions from atomic distortion and quadrupole distortion to the binary absorption coefficient are calculated for N2 and O2." @default.
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- W2062736834 date "1984-07-01" @default.
- W2062736834 modified "2023-09-24" @default.
- W2062736834 title "Collision-induced absorption of infrared radiation by N2, O2 and CO2" @default.
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- W2062736834 doi "https://doi.org/10.1016/0301-0104(84)85117-4" @default.
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