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• W2062751638 abstract "The synthesis of macroporous perovskite La0.65Sr0.3CoO3-δ and spinel NiCo2O4 electrodes was achieved by infiltration of La0.65Sr0.3CoO3-δ and NiCo2O4 colloid solutions inside a polymer gel template followed by calcination at 1100 °C to obtain single-phase materials. Resulting inorganic materials are porous and have a high specific surface area up to 90 m2 g-1, average pore diameter ∼450 nm, and 20−50 nm particle size. The structure of inorganic networks shows obvious similarities to the initial polymer gel network. Porous NiCo2O4 spinel can also be obtained from a precursor salt solution, whereas La0.65Sr0.3CoO3-δ perovskite formed after template impregnation from a precursor salt solution has a dense structure with a low specific surface area. Macroporous inorganic networks exhibit high electrocatalytic activity toward oxygen evolution from alkaline water solutions with the efficiency substantially better than that of the film electrodes having a similar composition. The highest activity was observed for the La0.65Sr0.3CoO3-δ perovskite network." @default.
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• W2062751638 date "2005-08-27" @default.
• W2062751638 modified "2023-10-18" @default.
• W2062751638 title "Polymer Gel Templating Synthesis of Nanocrystalline Oxide Anodes" @default.
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• W2062751638 doi "https://doi.org/10.1021/cm050672u" @default.
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