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- W2062757589 abstract "Previously published and new experimental data concerning the decay of electronically excited Hg atoms in low-temperature matrices are discussed on the basis of calculated potential-energy surfaces and electronic wavefunctions of the (Hg·N2)* system. The temperature dependence of the spectrum, quantum yield and lifetime of the UV emission from the exciplex (Hg·N2)* state is explained by two independent temperature effects on the |0− > ↔ |0+ > mixing and on the branching ratio between the electronic and vibrational relaxation of the vibrationally hot (Hg·N2)*# state prepared by the optical excitation. The efficient deactivation of the vibrationally excited Hg(N2)# centers by the electronic excitation of Hg is reported and the mechanism of this process is discussed." @default.
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- W2062757589 date "1989-09-01" @default.
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- W2062757589 title "Mechanism of Hg(3P1) relaxation in nitrogen matrices. II. Experimental results and interpretation" @default.
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- W2062757589 doi "https://doi.org/10.1016/0301-0104(89)80124-7" @default.
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