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• W2062765859 abstract "The reaction of MCl4 with K[HB(3,5-Me2Pz)3] in THF gives the monosubstituted derivatives M[HB(3,5-Me2Pz)3]Cl3(THF) (M=Th (1) and U (2)) in excellent yields. The NMR spectra of the molecules indicate symmetrical structures with equivalent pyrazolyl groups. This has been corroborated by single-crystal X-ray analysis. The uranium center in 2 is seven-coordinate and displays capped octahedral geometry. The tridentate pyrazolylborate moiety and the three Cl atoms define the two staggered triangular faces respectively, the latter is capped by the THF oxygen. The coordination geometry is close to C3v symmetry. The steric congestion imposed by the bulky pyrazolylborate ligand is evidenced by the relative low coordination number and the long U—O bond length, 2.546(4) Å. Crystal data 2: monoclinic, P21/n, a=10.195(2), b=14.905(2), c=17.414(4) Å, β=100.08(2)°, V= 2605.32 Å3 and Z=4. Complex 1 is isomorphous with 2." @default.
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• W2062765859 date "1987-09-01" @default.
• W2062765859 modified "2023-10-17" @default.
• W2062765859 title "Actinide poly(pyrazol-1-yl)borate complexes: synthesis and structure of hydrotris(3,5-dimethylpyrazol-1-yl)boratotrichlorotetrahydrofuran actinide(IV), M[HB(3,5-Me2Pz)3] Cl3(THF) (M=Th and U)" @default.
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• W2062765859 doi "https://doi.org/10.1016/s0020-1693(00)84003-7" @default.
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