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• W2062771608 abstract "The A-site ordered perovskite oxide CdCu3Mn4O12 has been synthesized for the first time in polycrystalline form under high pressure (7 GPa) and high temperature (1000 °C) conditions, required to stabilize the small Cd and Cu cations at the A positions of the perovskite. The crystal structure has been studied by X-ray powder diffraction at room temperature. This oxide crystallizes in the cubic space group Im3̅ (no. 204) with the unit-cell parameter a = 7.2179(5) Å at 300 K. The MnO6 network is extremely tilted, giving rise to a square planar coordination for Cu2+ cations. The magnetic characterization shows that this compound is ferrimagnetic with an ordering temperature TC = 347 K, well above room temperature. A metallic behavior is displayed between 10 and 300 K. Negative magnetoresistance (MR) of 15% is achieved at 10 K for H = 9 T; MR is still significant at room temperature, displaying values above 7% for H = 9 T. Density functional theory calculations carried out on the density of states lead to electronic and magnetic features in good agreement with the obtained experimental results." @default.
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• W2062771608 date "2014-04-25" @default.
• W2062771608 modified "2023-10-18" @default.
• W2062771608 title "Preparation, Crystal Structure, and Magnetotransport Properties of the New CdCu₃Mn₄O₁₂ Perovskite: A Comparison with Density Functional Theory Calculations" @default.
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• W2062771608 doi "https://doi.org/10.1021/jp500562e" @default.
• W2062771608 hasPublicationYear "2014" @default.
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