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- W2062783251 abstract "The syntheses of oligothiophenes 1 and 2 comprising two different types of peripheral substituents, namely alkyl and perfluoroalkyl, is reported. The key synthetic step is the Pd-catalyzed cross-coupling of perfluoroalkylated bromide 3 with an appropriate boronate. This molecular design is expected to promote unusual two-layer packing, which is of interest for application in electronic devices. Quaterthiophene 1 forms smectic mesophase, though in the narrow temperature range, and is suitable for the fabrication of thin films by solution processing methods." @default.
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- W2062783251 date "2007-01-01" @default.
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- W2062783251 title "Non-symmetrical oligothiophenes with ‘incompatible’ substituents" @default.
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- W2062783251 doi "https://doi.org/10.1016/j.tet.2006.11.029" @default.
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