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- W2062795303 abstract "Tungstate ions may be reversibly reduced at platinum, rhodium and mercury electrodes in phosphoric acid according to the reaction WO42-+e- ⇌ WO43-. The specific rate constants (ks) on Pt, Rh and Hg are 1.2.10-2, 7.0.10-3, and 6.5.10-4 cm/sec, respectively. In the presence of carbon monoxide, hydrogen evolution at Pt and Rh is blocked while the electron transfer for tungstate reduction is unhindered. This is used as a criterion for a surface dissociation or recombination step in an electrochemical reaction. Two methods may be used with platinum or rhodium electrodes for the determination of tungstate, either rotating the electrode at a constant speed and measuring the diffusion current, or measuring the reduction peak height at a constant potential scan rate." @default.
- W2062795303 created "2016-06-24" @default.
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- W2062795303 date "1967-01-01" @default.
- W2062795303 modified "2023-09-25" @default.
- W2062795303 title "Electrode reactions of tungstate ions in the presence of carbon monoxide" @default.
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