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- W2062801398 abstract "Materials with the general formula, Cu2ZnSnX4 (CZTX; X: Group 16 elements), with X being S/Se, have been receiving considerable attention due to their utility as an absorber layer in solar photovoltaics (PV). This paper reports on the synthesis of CZTSe and CZTS nanocrystalline powders at low temperatures, starting from elemental metal and chalcogen powders, via the low cost, scalable technique of ball milling. The prepared samples were well characterized using the different characterization tools. XRD, Raman, SEM and TEM studies confirm the formation of single-phase, stoichiometric, nano-crystalline kesterite CZTS and CZTSe powders. The low temperature phase selection of the complex quaternary compound in this system is seen as a direct consequence of the thermodynamic facilitation, coupled with the capability of mechano-chemical synthesis to aid in overcoming kinetic constraints. The optical bandgap of the various samples of CZTS was observed in the range of 1.4–1.6 eV and corresponding values for CZTSe was observed to be in the range of 1.08–1.18 eV. Our work provides a pathway for developing cheap, scalable, and ink-based techniques for low cost solar PV." @default.
- W2062801398 created "2016-06-24" @default.
- W2062801398 creator A5006866145 @default.
- W2062801398 creator A5040709533 @default.
- W2062801398 creator A5090598241 @default.
- W2062801398 date "2015-05-01" @default.
- W2062801398 modified "2023-09-26" @default.
- W2062801398 title "Synthesis and characterization of bulk Cu2ZnSnX4 (X: S, Se) via thermodynamically supported mechano-chemical process" @default.
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- W2062801398 doi "https://doi.org/10.1016/j.matchar.2015.03.014" @default.
- W2062801398 hasPublicationYear "2015" @default.
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