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- W2062810596 abstract "The reaction between RhHCl2(PPh3)3 and Hg(C6H5)2 yields the five-coordinate, 16-electron rhodium(III) complex Rh(C6H5)Cl2(PPh3)2. The molecular structure was determined by single-crystal X-ray diffraction (triclinic, P1, a = 9.532(28), b = 9.523(24), c = 21.800(19) Å, α = 112.9(1), β = 85.9(1), γ = 94.0(1)°, Z = 2). Rh(C6H5)Cl2(PPh3)2 exhibits square pyramidal geometry with close approach of two of the ortho hydrogen atoms of the triphenylphosphine ligands to the rhodium atom." @default.
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- W2062810596 date "1992-12-01" @default.
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- W2062810596 title "Synthesis and structure of the coordinatively unsaturated σ-aryl rhodium(III) complex Rh(C6H5)Cl2(PPh3)2" @default.
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- W2062810596 doi "https://doi.org/10.1016/s0020-1693(00)85359-1" @default.
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