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• W2062821156 abstract "We investigated the electronic states and structural properties of LixMn(Fe(CN)6)0.83·3.5H2O, and LixMn(Fe(CN)6)0.87·2.6H2O, which have different amount of (Fe(CN)6) vacancies. X-ray absorption spectra near the Fe and Mn K-edges revealed that the Li intercalation/deintercalation process is two-electron reaction, i.e. Mn II —NC—Fe II , Mn II — NC—Fe III , and Mn III —NC—Fe III . The crystal structure of LixMn(Fe(CN)6)0.83·3.5H2O remains cubic and single phase throughout the Li intercalation/deintercalation process. The crystal structure of LixMn(Fe(CN)6)0.87·2.6H2O is also cubic, while phase separation of Li + -rich phase and Li + -poor phase was observed during the Mn II /Mn III reduction/oxidation process." @default.
• W2062821156 created "2016-06-24" @default.
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• W2062821156 date "2013-04-05" @default.
• W2062821156 modified "2023-09-26" @default.
• W2062821156 title "Lithium intercalation properties in manganese-iron Prussian blue analogues" @default.
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• W2062821156 doi "https://doi.org/10.1088/1742-6596/428/1/012019" @default.
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