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- W2062843311 abstract "Most single-phase multiferroics are of perovskite (or narrowly related) crystal structure. N. Hill pointed out the significant drawback of this kind of materials for multiferroism: as ferromagnetism (requiring ’’d’’ configuration) and ferroelectricity (favoured by ’’d’’ configuration) rely on the same cationic sublattice, this one should contain both ’’d’’ and ’’d’’ cations. This condition is hardly fulfillable and most of the multiferroic materials currently studied are derived frommagnetic materials and do not contain ’’ferroelectrically active’’ cations such as Ti, Nb, Ta ... Our crystal-chemistry driven approach is to elaborate potentially multiferroic materials from ferroelectrics in which wemay substitute magnetic cations without significant alteration of the ’’ferroelectric framework’’. Ferroelectrics possessing several cationic sublattices are the most likely candidates, and in the wide range of ferroelectric materials studied at the ICMCB, Tetragonal Tungsten Bronzes (TTB) appear to be the ideal ones. Wewill present the structural, dielectric andmagnetic properties of substituted TTB niobates, the multiferroic properties of which will be discussed in terms of crystal-chemistry. A survey of the ’’core-shell multiferroic composites’’ activities at the ICMCB will be also given." @default.
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- W2062843311 date "2006-08-06" @default.
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- W2062843311 title "Crystal-chemistry design of new single-phase multiferroics" @default.
- W2062843311 doi "https://doi.org/10.1107/s0108767306097601" @default.
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