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- W2062871167 abstract "Abstract Two aluminium and magnesium heterobimetallic complexes of [(LAl)MgOBn] 2 ( 2 ) and [(LAl)Mg(OC 2 H 4 OCH 3 )] 2 ( 3 ), in which L = N 1 , N 1 , N 2 , N 2 ‐tetrakis(2‐hydroxy‐3,5‐dimethylbenzyl)‐1,2‐ethanediamine, have been synthesized and characterized by NMR spectroscopy, X‐ray crystallography, and elemental analysis. The magnesium alkoxide of complex 2 supported by the bulky aluminium tetraphenolates, as a rare helical heterobimetallic initiator, can effectively initiate the ring‐opening polymerization (ROP) of L ‐lactide ( L ‐LA) leading to polymers with good molecular weight control and narrow molecular weight distributions. Kinetic studies have shown the overall rate expression is –d[lactide]/d t = k [lactide][complex] for the ROP of L ‐LA. Furthermore, complex 2 shows modest isotactic selectivity in the ROP of rac ‐lactide." @default.
- W2062871167 created "2016-06-24" @default.
- W2062871167 creator A5008244867 @default.
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- W2062871167 creator A5058066900 @default.
- W2062871167 creator A5076544107 @default.
- W2062871167 creator A5080521536 @default.
- W2062871167 date "2013-06-04" @default.
- W2062871167 modified "2023-10-10" @default.
- W2062871167 title "Synthesis and Characterization of Magnesium Alkoxides Incorporated into Bulky Aluminium Tetraphenolate Helices and Application in the Ring‐Opening Polymerization of Lactides" @default.
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