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- W2062894570 abstract "A double diastereoselective glucosidation procedure giving rise in one step to the natural (2R)-2-β-configuration of 6 and, for the first time, 7, benzoxazinoid acetal glucosides from Gramineae species, is described by reaction of O-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl) trichloroacetimidate 3 as glucosyl donor with 2,4-dihydroxy-2H-1,4-benzoxazin-3(4H)-one 1 or its 7-methoxy derivative 2 as hemiacetalic glucosyl acceptors in the presence of excess borontrifluoride etherate as promoter without a need for a covalent protection of the cyclic hydroxamic acid unit in the aglucones." @default.
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- W2062894570 title "Double diastereoselective glucosidation of cyclic hemiacetals: Synthesis of the 1,4-benzoxazinone acetal glucosides GDIBOA and GDIMBOA from Gramineae" @default.
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