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- W2062913191 abstract "The electrochemical and electrochromic properties of layer-by-layer nanoarchitectures of V2O5/chitosan and V2O5 alternated with a blend of poly(ethylene oxide) (PEO) and chitosan have been examined. Using a blend was important, since multilayers of PEO/V2O5 could not be built. The number of electrochemically active V2O5 sites was estimated to be around 3.4 × 10–8 mol cm–2 and 4.4 × 10–8 mol cm–2 for V2O5/chitosan and V2O5/blend, respectively, based on the UV-vis absorbance attributed to the intervalence V4+→V5+ transfer. A pronounced effect from PEO was observed in the migration/diffusion process, according to cyclic voltammetry and impedance spectroscopy data. The charges injected were 3.29 mC cm–2 and 8.02 mC cm–2 for V2O5/chitosan and V2O5/blend, respectively, at 20 mV s–1. For V2O5/blend, the chronopotentiometric curves show that x in LixV2O5 is about 1.77. Evidence of enhanced ionic transport was provided by the Fourier transform infrared (FTIR) spectrum, which indicated lithium complexation by PEO and formation of a larger amorphous phase of PEO within the V2O5 matrix. The importance of these results for the production of Li secondary microbatteries and electrochromic devices is discussed." @default.
- W2062913191 created "2016-06-24" @default.
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- W2062913191 date "2004-10-01" @default.
- W2062913191 modified "2023-09-23" @default.
- W2062913191 title "Charge Storage Capability in Nanoarchitectures of V2O5/Chitosan/Poly(ethylene oxide) Produced Using the Layer-by-Layer Technique" @default.
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- W2062913191 doi "https://doi.org/10.1002/adfm.200305077" @default.
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