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- W2062917085 abstract "The synthesis and crystal structure of the title compound obtained by reaction of copper perchlorate with 5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine (dmtp) are reported. The structure consists of [Cu(dmtp)3(H20)2] coordination cations, CIO4 anions and interstitial water molecules. The Cu atom is coordinated by three N(3) atoms of triazolopyrimidine ligands [Cu--N = 1.985 (5), 1.993 (4), 2.024 (4)A] and two aqueous O atoms [Cu---O = 1.979 (4), 2.245 (4)A]. The Cu polyhedron is a trigonal bipyramid. This compound is the first dmtp complex with a C104 anion and the first mononuclear complex involving three dmtp ligands, and whose crystal structure has been solved by X-ray diffraction." @default.
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- W2062917085 date "1993-11-15" @default.
- W2062917085 modified "2023-09-25" @default.
- W2062917085 title "Structure of diaquatris(5,7-dimethyl[1,2,4]triazolo[1,5-a]pyrimidine-N3)copper(II) perchlorate dihydrate" @default.
- W2062917085 doi "https://doi.org/10.1107/s0108270193004196" @default.
- W2062917085 hasPublicationYear "1993" @default.
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