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- W2062922174 abstract "Abstract The interaction of recoil tritium (T), with an initial kinetic energy of 2.7 MeV with C 60 molecules, is studied in a 6 Li ( n , α ) T activated homogenized compound matrix of Li 2 CO 3 and C 60 . Liquid scintillation spectrometry coupled with high pressure liquid chromatography (HPLC) revealed endohedral T insertion into the fullerene cage upon extraction of the fullerene species into the organic phase. Solid state temperature programmed desorption profiles of the activated compound target showed the desorption of 3 He gas (as a β − decay product from T) from the endohedral T@C 60 at 882 °C. The deconvoluted evolved gas analysis–mass spectral (EGA–MS) data provided a 25% probability of T@C 60 formation upon nuclear activation of the compound target. The non-isothermal kinetics of the tritium desorption, studied as a function of temperature, revealed the process to be diffusion controlled." @default.
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- W2062922174 date "2001-11-01" @default.
- W2062922174 modified "2023-09-23" @default.
- W2062922174 title "Thermal desorption of 3He from T@C60" @default.
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- W2062922174 doi "https://doi.org/10.1016/s0009-2614(01)01212-x" @default.
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