Matches in SemOpenAlex for { <https://semopenalex.org/work/W2062937593> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2062937593 endingPage "5633" @default.
- W2062937593 startingPage "5626" @default.
- W2062937593 abstract "The syntheses of several cyclophanes containing a triaryl(element) top poised above a trisubstituted benzene base were carried out to install a non-hydrogen atom as a substituent on a bridgehead with an inwardly directed geometry. Most significantly, the tribenzo 6-fluoro-6-sila-2,10,19-trithia[5(6,14)][11]metacyclophane 2 was prepared by condensation of tris[2-(bromomethyl)phenyl]fluorosilane and 1,3,5-tris(mercaptomethyl)benzene in 0.4% yield. The X-ray structure of 2 shows that the cyclophane adopts an in-configuration; i.e., the fluorine atom is on the interior of the macrocycle and only 2.8 Å from the center of the basal aromatic ring. Compound 2 is one of only a very few molecules to contain a non-hydrogen in-atom, and the in-fluorosilane of 2 is the largest in-functional group to have been installed in any molecule. Similar attempts to prepare an in-phosphine oxide were unsuccessful, although the corresponding in-phosphines were prepared, and an attempt to prepare an in-methylsilane led instead to the corresponding out-isomer." @default.
- W2062937593 created "2016-06-24" @default.
- W2062937593 creator A5032167881 @default.
- W2062937593 creator A5042583592 @default.
- W2062937593 creator A5047662881 @default.
- W2062937593 date "1999-07-01" @default.
- W2062937593 modified "2023-10-18" @default.
- W2062937593 title "<i>in-</i> and <i>out-</i>Cyclophanes Bearing Non-Hydrogen Bridgehead Substituents" @default.
- W2062937593 cites W1563954963 @default.
- W2062937593 cites W1987741028 @default.
- W2062937593 cites W2009046603 @default.
- W2062937593 cites W2039337052 @default.
- W2062937593 cites W2056323885 @default.
- W2062937593 cites W2056601364 @default.
- W2062937593 cites W2059086088 @default.
- W2062937593 cites W2062370334 @default.
- W2062937593 cites W2080586491 @default.
- W2062937593 cites W2084263633 @default.
- W2062937593 cites W2087565362 @default.
- W2062937593 cites W2333626019 @default.
- W2062937593 cites W2463506420 @default.
- W2062937593 cites W2949867616 @default.
- W2062937593 doi "https://doi.org/10.1021/jo990727+" @default.
- W2062937593 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11674632" @default.
- W2062937593 hasPublicationYear "1999" @default.
- W2062937593 type Work @default.
- W2062937593 sameAs 2062937593 @default.
- W2062937593 citedByCount "27" @default.
- W2062937593 countsByYear W20629375932012 @default.
- W2062937593 countsByYear W20629375932013 @default.
- W2062937593 countsByYear W20629375932014 @default.
- W2062937593 countsByYear W20629375932017 @default.
- W2062937593 countsByYear W20629375932020 @default.
- W2062937593 crossrefType "journal-article" @default.
- W2062937593 hasAuthorship W2062937593A5032167881 @default.
- W2062937593 hasAuthorship W2062937593A5042583592 @default.
- W2062937593 hasAuthorship W2062937593A5047662881 @default.
- W2062937593 hasConcept C155647269 @default.
- W2062937593 hasConcept C161790260 @default.
- W2062937593 hasConcept C178790620 @default.
- W2062937593 hasConcept C185592680 @default.
- W2062937593 hasConcept C2776640939 @default.
- W2062937593 hasConcept C2777691172 @default.
- W2062937593 hasConcept C2777716191 @default.
- W2062937593 hasConcept C2778624557 @default.
- W2062937593 hasConcept C2778689049 @default.
- W2062937593 hasConcept C2780378348 @default.
- W2062937593 hasConcept C2781014771 @default.
- W2062937593 hasConcept C2781082197 @default.
- W2062937593 hasConcept C2781311116 @default.
- W2062937593 hasConcept C32909587 @default.
- W2062937593 hasConcept C506198293 @default.
- W2062937593 hasConcept C55493867 @default.
- W2062937593 hasConcept C71240020 @default.
- W2062937593 hasConcept C8010536 @default.
- W2062937593 hasConceptScore W2062937593C155647269 @default.
- W2062937593 hasConceptScore W2062937593C161790260 @default.
- W2062937593 hasConceptScore W2062937593C178790620 @default.
- W2062937593 hasConceptScore W2062937593C185592680 @default.
- W2062937593 hasConceptScore W2062937593C2776640939 @default.
- W2062937593 hasConceptScore W2062937593C2777691172 @default.
- W2062937593 hasConceptScore W2062937593C2777716191 @default.
- W2062937593 hasConceptScore W2062937593C2778624557 @default.
- W2062937593 hasConceptScore W2062937593C2778689049 @default.
- W2062937593 hasConceptScore W2062937593C2780378348 @default.
- W2062937593 hasConceptScore W2062937593C2781014771 @default.
- W2062937593 hasConceptScore W2062937593C2781082197 @default.
- W2062937593 hasConceptScore W2062937593C2781311116 @default.
- W2062937593 hasConceptScore W2062937593C32909587 @default.
- W2062937593 hasConceptScore W2062937593C506198293 @default.
- W2062937593 hasConceptScore W2062937593C55493867 @default.
- W2062937593 hasConceptScore W2062937593C71240020 @default.
- W2062937593 hasConceptScore W2062937593C8010536 @default.
- W2062937593 hasIssue "15" @default.
- W2062937593 hasLocation W20629375931 @default.
- W2062937593 hasLocation W20629375932 @default.
- W2062937593 hasOpenAccess W2062937593 @default.
- W2062937593 hasPrimaryLocation W20629375931 @default.
- W2062937593 hasRelatedWork W2055787245 @default.
- W2062937593 hasRelatedWork W2059288820 @default.
- W2062937593 hasRelatedWork W2159447291 @default.
- W2062937593 hasRelatedWork W2170631982 @default.
- W2062937593 hasRelatedWork W2322208265 @default.
- W2062937593 hasRelatedWork W2911718904 @default.
- W2062937593 hasRelatedWork W2951795391 @default.
- W2062937593 hasRelatedWork W3011824861 @default.
- W2062937593 hasRelatedWork W3015795223 @default.
- W2062937593 hasRelatedWork W4231755602 @default.
- W2062937593 hasVolume "64" @default.
- W2062937593 isParatext "false" @default.
- W2062937593 isRetracted "false" @default.
- W2062937593 magId "2062937593" @default.
- W2062937593 workType "article" @default.