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- W2062956354 abstract "Polycrystalline samples of ammonium fluorotellurates NH4TeF5 and (NH4)2TeF6 have been investigated using RAMAN spectroscopic techniques. The study has been limited by the absorption of the laser light that easily decomposes the samples. Compared to previously recorded spectra, the RAMAN spectra of NH4TeF5 show new features below 100 cm−1 and at about 3200 and 1100 cm−1. A vibrational analysis has been performed and observed frequencies have been assigned to internal modes of NH4+ and TeF5− ions and to external modes. The RAMAN spectra of (NH4)2TeF6 have been recorded in the range 20 → 1000 cm−1. RAMAN frequencies have been assigned assuming an Oh symmetry for the TeF62− ion. Force constant calculations have been performed using simple force field models." @default.
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- W2062956354 date "1986-03-01" @default.
- W2062956354 modified "2023-09-26" @default.
- W2062956354 title "Etude par diffusion raman des fluorotellurates IV d'ammonium NH4TeF5 et (NH4)2TeF6 solides" @default.
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- W2062956354 doi "https://doi.org/10.1016/0025-5408(86)90192-3" @default.
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