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• W2063014742 endingPage "3014" @default.
• W2063014742 startingPage "3006" @default.
• W2063014742 abstract "We present a study of the application of deuteron-nuclear magnetic resonance spectroscopy (NMR) to the investigation of the rotational diffusion of spherical colloidal particles. We performed NMR pulse experiments on colloidal suspensions of polystyrene latex spheres in water-glycerol mixtures in a wide range of particle volume fractions ensuremath{varphi} from the dilute suspension up to ensuremath{varphi}=0.504. We have analyzed the stimulated echo NMR signal in the time domain. The full shape of the orientational correlation function deviates from an exponential behavior in the whole ensuremath{varphi} range examined. We evaluate the rotational diffusion coefficient and calculate its ensuremath{varphi} dependence up to the ${mathrm{ensuremath{varphi}}}^{2}$ term in view of the theory proposed recently [V. Degiorgio, R. Piazza, and R. B. Jones, Phys. Rev. E 52, 2707 (1995)], which considers the effect of two- and three-body hydrodynamic interactions upon particle reorientation. We find considerable slowing down of sphere reorientation for ensuremath{varphi}ensuremath{geqslant}0.2. The agreement between experimental results and theoretical considerations is satisfactory." @default.
• W2063014742 created "2016-06-24" @default.
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• W2063014742 date "1997-03-01" @default.
• W2063014742 modified "2023-09-30" @default.
• W2063014742 title "Rotational diffusion of colloid spheres in concentrated suspensions studied by deuteron NMR" @default.
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• W2063014742 doi "https://doi.org/10.1103/physreve.55.3006" @default.
• W2063014742 hasPublicationYear "1997" @default.
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