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• W2063023444 abstract "The behavior of benzene molecules in ZSM-5 has been studied in detail with the use of diffuse reflectance FT-IR spectroscopy. The infrared difference spectra indicate that benzene molecules have a high selectivity for adsorption first on the most energetic (Brönsted acid) ZSM-5 sites. The existence of at least two adsorbed benzene species has also been confirmed by infrared spectroscopy. Deuterated benzene (C 6 D 6 ) species located at the ZSM-5 channels and channel intersections are characterized by the C-D stretching vibrations at 2284 and 2276 cm −1 , respectively. Since the high symmetry ( D 6h ) of the adsorbed benzene molecules is preserved, the framework of ZSM-5 may have been distorted. The distortion of the framework of ZSM-5 is also indicated by the red shift of the Si-O (or Al-O) asymmetric stretching vibrations (at ∼1215 cm −1 ) when adsorbed benzene molecules are present." @default.
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• W2063023444 date "1990-07-01" @default.
• W2063023444 modified "2023-09-23" @default.
• W2063023444 title "Benzene in Zeolite ZSM-5 Studied by Diffuse Reflectance Infrared Spectroscopy" @default.
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• W2063023444 doi "https://doi.org/10.1366/0003702904086902" @default.
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