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- W2063035215 abstract "A novel mesoporous material covalently bonded with 8-hydroxyquinoline (HQ) was synthesized (designated as Q−SBA-15). The 5-formyl-8-hydroxyquinoline grafted to (3-aminopropyl)triethoxysilane, that is, alkoxysilane modified 8-hydroxyquinoline (Q-Si), was used as one of the precursors for the preparation of the Q−SBA-15 material. On the basis of the other function of the Q-Si of coordinating to lanthanide (Ln) ions, for the first time, the LnQ3 complexes (Ln = Er, Nd, Yb) have been covalently bonded to the SBA-15 materials. The derivative materials, denoted as LnQ3−SBA-15, were characterized by field emission scanning electron microscopy (FE-SEM), powder X-ray diffraction (XRD), transmission electron microscopy (TEM), nitrogen adsorption–desorption, and fluorescence spectra. Upon excitation at the ligands absorption bands, all of these materials show the characteristic near-infrared (NIR) luminescence of the corresponding lanthanide ions through the intramolecular energy transfer from the ligands to the lanthanide ions. The NIR luminescence of these mesoporous materials was compared with that of the corresponding pure LnQ3 complexes and discussed in detail." @default.
- W2063035215 created "2016-06-24" @default.
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- W2063035215 date "2008-04-16" @default.
- W2063035215 modified "2023-09-24" @default.
- W2063035215 title "Near-Infrared Emission from Novel Tris(8-hydroxyquinolinate)lanthanide(III) Complexes-Functionalized Mesoporous SBA-15" @default.
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- W2063035215 doi "https://doi.org/10.1021/la7036108" @default.
- W2063035215 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18412375" @default.
- W2063035215 hasPublicationYear "2008" @default.
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