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- W2063043154 abstract "Single crystals of niobium-substituted α-Fe2O3 were grown by using chemical vapor transport with tellurium tetrachloride and were characterized by using bulk methods (X rays, resistivity, magnetism) and surface techniques (low-energy electron diffraction (LEED), Auger, X-ray photoelectron spectroscopy (XPS)). Niobium-substituted α-Fe2O3 crystallizes with the corundum structure, and is an extrinsic n-type semiconductor with a room temperature resistivity of approximately 85 Ω cm, and an activation energy for conductivity of 0.22 eV. Low-temperature susceptibility measurements suggest that the substitution of niobium(V) in octahedral sites leads to reduction of iron(III) to iron(II) without spinel phase inclusions. The main face of the single crystal platelets is the (001) basal plane of α-Fe2O3. The surface is very well ordered as shown by LEED. These crystals show good potential for application in both photoelectrochemistry and surface science studies." @default.
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- W2063043154 date "1986-01-01" @default.
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- W2063043154 title "Synthesis, bulk, and surface characterization of niobium-doped Fe2O3 single crystals" @default.
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- W2063043154 doi "https://doi.org/10.1016/0022-4596(86)90005-8" @default.
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