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• W2063046871 abstract "A new method for the catalytic enantioselective Strecker reaction (cyanation) of N-diphenylphosphinoyl ketoimines is described. The asymmetric catalyst is a chiral gadolinium complex prepared from Gd(OiPr)3 and the d-glucose-derived ligand 3 in a 1:2 ratio. The reaction has a broad substrate generality, giving high enantioselectivity from aromatic, ethyl, primary alkyl, and alpha,beta-unsaturated ketoimines. The products could be easily converted to disubstituted alpha-amino acids and their derivatives." @default.
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• W2063046871 date "2003-04-18" @default.
• W2063046871 modified "2023-10-16" @default.
• W2063046871 title "Catalytic Enantioselective Strecker Reaction of Ketoimines" @default.
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• W2063046871 doi "https://doi.org/10.1021/ja034980+" @default.
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