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- W2063072051 abstract "Abstract The reactions of the triply bonded complexes [Re2(μ-O2CCH3)X2(μ-dmpm)3] PF6 (X = Cl or Br; dmpm = Me2PCH2PMe2) with CO in deoxygenated acetone/HPF6(aq) mixtures afford the unusual dirhenium(II) carbonyl complexes [Re2(μ-X)2(μ-dmpm) (CO)2(dmpm)2(H2PO4)2 in which the ReRe bond is very long [2.918(2) A for X = Cl]. These reactions are accompanied by the switch of two of the bridging dmpm ligands to a chelating mode." @default.
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- W2063072051 title "The carbonylation of [Re2(μ-O2CCH3)X2 (μ-dmpm)3]PF6 (X = Cl OR Br; dmpm = Me2PCH2PME2) involving a switch in the binding of two of the dmpm ligands from bridging to chelating" @default.
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