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- W2063086482 abstract "Group-IV-A phthalocyanines with four crown ether substituents have been prepared from 4′,5′-dicyanobenzo(15-crown-5), 4′,5′-diiminoisoindolino(15-crown-5), or metal-free phthalocyanine and the corresponding metal salts. The axial ligands of dichloro[tetra(15-crown-5)phthalocyaninato]silicon or -tin have been converted into dihydroxy derivatives by hydrolysis in aqueous Et3N. The catalytic effect of H2O-free CaC12 in quinoline is used for the polycondensation of dihydroxysilicon-phthalocyanine to cofacially arrayed polymers. The thermal stability of group-IV-A-metal phthalocyanines is confirmed by the higher initial decomposition points (290–440°) compared to those of the corresponding transition-metal phthalocyanines." @default.
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- W2063086482 date "1988-11-02" @default.
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- W2063086482 title "Synthesis and Characterization of Crown-Ether-Containing Phthalocyanines with Group-IV-A Elements" @default.
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- W2063086482 doi "https://doi.org/10.1002/hlca.19880710705" @default.
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