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- W2063088045 abstract "A new three-dimensional open-framework cobalt-zinc phosphite [Co(H2O)4Zn(HPO3)2]·H2O (1), has been prepared under hydrothermal conditions and characterized by single-crystal X-ray diffraction, XRD, IR and SQUID magnetometer. The compound crystallizes in the triclinic space group with a = 7.552(5), b = 7.671(5), c = 9.443(5) A, α = 88.538(5)°, β = 89.109(5)°, γ = 87.056(5)°, V = 546.1(6) A3, Z = 2. The structure of 1 consists of corner-shared (cs) four-membered-ring chains formed by alternating ZnO4 tetrahedra and HPO3 pseudopyramids, which are further linked through CoO2(H2O)4 octahedra giving rise to a three-dimensional (3-D) neutral open-framework with intersecting 12- and 16-MR channels. The synthesis of system required the presence of L-histidine which is not incorporated into the structure of the product. It is noteworthy that compound 1 represents the only known example of purely inorganic open-framework cobalt-zinc phosphite." @default.
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- W2063088045 date "2008-06-24" @default.
- W2063088045 modified "2023-10-05" @default.
- W2063088045 title "ChemInform Abstract: Synthesis and Characterization of a Purely Inorganic Open-Framework Bimetallic Phosphite with Intersecting 12- and 16-Membered Ring Channels." @default.
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- W2063088045 doi "https://doi.org/10.1002/chin.200826024" @default.
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