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- W2063092384 abstract "SN2′-type substitution on allylic systems can provide an attractive route to chiral molecules. The authors report a Cu-TaniaPhos system which catalyzes allylic substitutions of allylic bromides using Grignard reagents to provide a terminal olefin. Various linear Grignard reagents could be introduced onto functionalized substrates in high yield and ee with superb regioselectivity. The utility of this transformation is demonstrated through functionalization of the newly formed terminal olefin to provide various optically active bifunctional molecules." @default.
- W2063092384 created "2016-06-24" @default.
- W2063092384 date "2007-05-22" @default.
- W2063092384 modified "2023-10-14" @default.
- W2063092384 title "Copper-Catalyzed Asymmetric Allylic Alkylation Using Grignard Reagents" @default.
- W2063092384 doi "https://doi.org/10.1055/s-2007-968502" @default.
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