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- W2063116201 abstract "Abstract A thermodynamic framework for evaluating the mixed pressure (P), temperature (T) and derivative of bulk modulus ( ∂ 2 B T / ∂ P ∂ T ) is developed under the assumption that the pure thermal derivative of isothermal bulk modulus (∂BT/∂T)V is zero. An analysis of the thermodynamic consequences of this assumption led to the following approximations for ∂ 2 B T /∂P ∂T : (i) ( ∂ 2 B T / ∂ P ∂ T)=δ T α V ; (ii) ( ∂ 2 B T / ∂ P ∂T)=(γ G /b)( ∂ C V / ∂ P) T and (iii) ( ∂ 2 B T / ∂ P ∂T)=kC P , where δT, αV, γG, CP, CV stand, respectively, for the isothermal Anderson–Gruneisen parameter, isobaric volume thermal expansivity, thermal Gruneisen parameter, isobaric and isochoric specific heats. The temperature-independent thermoelastic constants b and k represent ( ∂ ln B T / ∂ V) P −1 and ( ∂ ln B T / ∂ H) P , respectively. The approximations developed in this study are applied to MgO and the estimated ( ∂ 2 B T / ∂ P ∂ T) values compare favourably with the experimental results." @default.
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- W2063116201 date "2002-11-01" @default.
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- W2063116201 title "Thermodynamic approximations for the mixed temperature and pressure derivative of bulk modulus: a case study on MgO" @default.
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