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• W2063118886 endingPage "2186" @default.
• W2063118886 startingPage "2179" @default.
• W2063118886 abstract "The first trans-ruthenium complex trans-[Ru(DIP)2(MeOH)2][OTf]2 (1b, where DIP = 4,7-diphenyl-1,10-phenanthroline) incorporating a π-extended ligand was prepared via two methods: either photolysis of cis-[Ru(DIP)2(OTf)2] in MeOH–Et2O or via crystallization from MeOH–Et2O in direct sunlight. The X-ray molecular structure of 1b is reported and confirmed the trans geometry of the title compound. The cis–trans isomerization process was monitored by 1H-NMR and showed that 1b reverts back to cis-[Ru(DIP)2(MeOH)2][OTf]2 (1a) in methanol-d4 after 15 h at 55 °C or several days at room temperature. The absorption spectra recorded in MeOH showed a bathochromic shift of the MLCT band of the trans-isomer 1b relative to that of the cis complex 1a. Interestingly at 77 K the emission spectrum of 1b is red shifted compared to the cis analog 1a. A rational explanation in terms of the energy of the excited states in the cis- and trans-isomers is proposed to explain this behavior." @default.
• W2063118886 created "2016-06-24" @default.
• W2063118886 creator A5001145040 @default.
• W2063118886 creator A5031132995 @default.
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• W2063118886 creator A5041073658 @default.
• W2063118886 creator A5041401447 @default.
• W2063118886 creator A5082677184 @default.
• W2063118886 date "2007-01-01" @default.
• W2063118886 modified "2023-10-10" @default.
• W2063118886 title "cis–trans Photoisomerization in [Ru(DIP)₂(MeOH)₂][OTf]₂: synthesis, NMR, X-ray structure of the trans-isomer and photophysical properties" @default.
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• W2063118886 doi "https://doi.org/10.1039/b701089c" @default.
• W2063118886 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/17514339" @default.
• W2063118886 hasPublicationYear "2007" @default.
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