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• W2063178276 abstract "The postulated low thermal conductivity and the possibility of altering the electronic conductivity of metal-doped clathrates with semiconducting host elements have stimulated great interest in exploring these compounds as promising thermoelectric materials. The electronic and thermal properties of the prototypical $mathrm{Na}{}_{x}mathrm{Si}{}_{46}$ system are studied in detail here. It is shown that, despite the fact that the $mathrm{Na}/mathrm{Si}$ clathrate is metallic, its thermal conductivity resembles that of an amorphous solid. A theoretical model is developed to rationalize the structural stability of the peculiar structural topology, and a general scheme for rational design of high efficiency thermoelectric materials is presented." @default.
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• W2063178276 date "2000-07-03" @default.
• W2063178276 modified "2023-09-23" @default.
• W2063178276 title "Structural Principles and Amorphouslike Thermal Conductivity of Na-Doped Si Clathrates" @default.
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• W2063178276 doi "https://doi.org/10.1103/physrevlett.85.114" @default.
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