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- W2063194920 abstract "Die optische Reinheit eines Produkts am Reaktorausgang hängt nicht nur von der Enantioselektivität des Katalysators ab, sondern auch von der Reaktorkonfiguration. Für die kinetische Racematspaltung werden verschiedene Reaktortypen in Hinblick auf den erzielbaren Enantiomerenüberschuss (ee) bei einem bestimmten Umsatz verglichen. Während für den kontinuierlich betriebenen Rührkesselreaktor ein hoher ee nur bei Enantioselektivitäten (E-Werte) von größer 190 erhalten wird, gelingt dies unter Batch-, Fed-batch- und Strömungsrohrbedingungen schon bei E-Werten von 35. The optical purity of a product at the reactor outlet depends not only on the enantioselectivity of the catalyst, but also on the reactor configuration. Different reactor configurations are compared with respect to the enantiomeric excess (ee) at a respective conversion that can be achieved in a kinetic resolution of a racemate. For batch, fed-batch and plug flow reactors enantioselectivities (E value) of 35 are sufficient to achieve high enantiomeric excess. For a continuously operated stirred tank reactor high ee values are only obtained for E values higher than 190." @default.
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- W2063194920 date "2013-04-26" @default.
- W2063194920 modified "2023-09-23" @default.
- W2063194920 title "Einfluss der Reaktorkonfiguration auf die Enantioselektivität einer kinetischen Racematspaltung" @default.
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