FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2063201110> ?p ?o ?g. }

• W2063201110 endingPage "11534" @default.
• W2063201110 startingPage "11523" @default.
• W2063201110 abstract "The molecular reorientation of liquid water is key to the hydration and stabilization of molecules and ions in aqueous solution. A powerful technique to study this reorientation is to measure the time-dependent anisotropy of the excitation of the O−H/O−D stretch vibration of HDO dissolved in D2O/H2O using femtosecond midinfrared laser pulses. In this paper, we present and discuss experiments in which this technique is used to study the correlation between the molecular reorientation of the water molecules and the strength of the hydrogen-bond interactions. On short time scales (<200 fs), it was found that the anisotropy shows a partial decay due to librational motions of the water molecules that keep the hydrogen bond intact. On longer time scale (>200 fs), the anisotropy shows a complete decay with an average time constant of 2.5 ps. From the frequency dependence of the anisotropy dynamics, it follows that a subensemble of the water molecules shows a fast reorientation that is accompanied by a large change of the vibrational frequency. This finding agrees with the molecular jumping mechanism for the reorientation of liquid water that has recently been proposed by Laage and Hynes." @default.
• W2063201110 created "2016-06-24" @default.
• W2063201110 creator A5042058145 @default.
• W2063201110 creator A5050763048 @default.
• W2063201110 creator A5071128058 @default.
• W2063201110 date "2008-10-28" @default.
• W2063201110 modified "2023-09-27" @default.
• W2063201110 title "Molecular Reorientation of Liquid Water Studied with Femtosecond Midinfrared Spectroscopy" @default.
• W2063201110 cites W1489396522 @default.
• W2063201110 cites W1563494356 @default.
• W2063201110 cites W1636236690 @default.
• W2063201110 cites W1966035771 @default.
• W2063201110 cites W1966108258 @default.
• W2063201110 cites W1969523390 @default.
• W2063201110 cites W1973889068 @default.
• W2063201110 cites W1975762035 @default.
• W2063201110 cites W1976636184 @default.
• W2063201110 cites W1981739010 @default.
• W2063201110 cites W1982219464 @default.
• W2063201110 cites W1987297119 @default.
• W2063201110 cites W1991352331 @default.
• W2063201110 cites W1991394389 @default.
• W2063201110 cites W2001888836 @default.
• W2063201110 cites W2005309347 @default.
• W2063201110 cites W2005420127 @default.
• W2063201110 cites W2026927223 @default.
• W2063201110 cites W2027186143 @default.
• W2063201110 cites W2029799575 @default.
• W2063201110 cites W2032318886 @default.
• W2063201110 cites W2037182498 @default.
• W2063201110 cites W2041190159 @default.
• W2063201110 cites W2044326923 @default.
• W2063201110 cites W2051698784 @default.
• W2063201110 cites W2054134130 @default.
• W2063201110 cites W2060549159 @default.
• W2063201110 cites W2061178260 @default.
• W2063201110 cites W2064141166 @default.
• W2063201110 cites W2069672553 @default.
• W2063201110 cites W2071077673 @default.
• W2063201110 cites W2071954294 @default.
• W2063201110 cites W2072225167 @default.
• W2063201110 cites W2073054601 @default.
• W2063201110 cites W2076528399 @default.
• W2063201110 cites W2083887156 @default.
• W2063201110 cites W2090083896 @default.
• W2063201110 cites W2090633123 @default.
• W2063201110 cites W2091825040 @default.
• W2063201110 cites W2097895571 @default.
• W2063201110 cites W2107941176 @default.
• W2063201110 cites W2114513310 @default.
• W2063201110 cites W2128097747 @default.
• W2063201110 cites W2131530553 @default.
• W2063201110 cites W2134464060 @default.
• W2063201110 doi "https://doi.org/10.1021/jp8012943" @default.
• W2063201110 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18954036" @default.
• W2063201110 hasPublicationYear "2008" @default.
• W2063201110 type Work @default.
• W2063201110 sameAs 2063201110 @default.
• W2063201110 citedByCount "84" @default.
• W2063201110 countsByYear W20632011102012 @default.
• W2063201110 countsByYear W20632011102013 @default.
• W2063201110 countsByYear W20632011102014 @default.
• W2063201110 countsByYear W20632011102015 @default.
• W2063201110 countsByYear W20632011102016 @default.
• W2063201110 countsByYear W20632011102017 @default.
• W2063201110 countsByYear W20632011102018 @default.
• W2063201110 countsByYear W20632011102019 @default.
• W2063201110 countsByYear W20632011102020 @default.
• W2063201110 countsByYear W20632011102021 @default.
• W2063201110 countsByYear W20632011102022 @default.
• W2063201110 countsByYear W20632011102023 @default.
• W2063201110 crossrefType "journal-article" @default.
• W2063201110 hasAuthorship W2063201110A5042058145 @default.
• W2063201110 hasAuthorship W2063201110A5050763048 @default.
• W2063201110 hasAuthorship W2063201110A5071128058 @default.
• W2063201110 hasConcept C112887158 @default.
• W2063201110 hasConcept C120665830 @default.
• W2063201110 hasConcept C121332964 @default.
• W2063201110 hasConcept C145148216 @default.
• W2063201110 hasConcept C147597530 @default.
• W2063201110 hasConcept C147789679 @default.
• W2063201110 hasConcept C159467904 @default.
• W2063201110 hasConcept C167735695 @default.
• W2063201110 hasConcept C178790620 @default.
• W2063201110 hasConcept C184651966 @default.
• W2063201110 hasConcept C184779094 @default.
• W2063201110 hasConcept C185592680 @default.
• W2063201110 hasConcept C2776294576 @default.
• W2063201110 hasConcept C2989277613 @default.
• W2063201110 hasConcept C32891209 @default.
• W2063201110 hasConcept C32909587 @default.
• W2063201110 hasConcept C41999313 @default.
• W2063201110 hasConcept C520434653 @default.
• W2063201110 hasConcept C58364064 @default.
• W2063201110 hasConcept C59593255 @default.
• W2063201110 hasConcept C62520636 @default.
• W2063201110 hasConcept C85725439 @default.
• W2063201110 hasConcept C97355855 @default.

• next