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• W2063252060 abstract "The effects of continuous sonication and presonication on the kinetics of oxidative dissolution of ruthenium dioxide hydrate by bromate ions under acidic conditions are reported. Compared with unsonicated and presonicated dispersions the overall rate of dissolution of continuously sonicated dispersions is significantly greater due to a reduction in the average particle size and, hence, an increase in the specific surface area. Powder dispersions subjected to continuous ultrasound and presonication exhibit an initial induction period in their corrosion kinetics; the length of this induction period increases with increasing presonication. This corrosion feature is retained in the dissolution kinetics of powder samples which have been subjected to pre-ultrasound, but which are then stirred during the dissolution process. It is believed that this apparent permanent change in the nature of the powder particles is due to the ultrasound induced formation of a very thin layer of a largely unreactive form of ruthenium dioxide (possibly due to partial dehydration) on the surface of the powder particles. A kinetic scheme, based on this model, is used to account for th e observed kinetics of dissolution of RuO2.xH2O which have been subjected to both continuous sonication and presonication." @default.
• W2063252060 created "2016-06-24" @default.
• W2063252060 creator A5026135770 @default.
• W2063252060 creator A5060038119 @default.
• W2063252060 date "1992-01-01" @default.
• W2063252060 modified "2023-09-27" @default.
• W2063252060 title "The effect of power ultrasound on the oxidative dissolution of RuO2.xH2O by bromate ions" @default.
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• W2063252060 doi "https://doi.org/10.1016/0041-624x(92)90008-a" @default.
• W2063252060 hasPublicationYear "1992" @default.
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