FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2063255731> ?p ?o ?g. }

• W2063255731 endingPage "2086" @default.
• W2063255731 startingPage "2078" @default.
• W2063255731 abstract "Spin-forbidden absorption bands of K3[Co(CN)6] were reexamined employing conventional transmission spectroscopy, diffuse reflectance spectroscopy, and microspectrophotometry. A small but very distinct shoulder (ε≈0.3–0.4) obtained at a low temperature at 26000 cm−1 was assigned to the 3T1g←1A1g transition. Another very small band (ε≈0.001) at 16300 cm−1 was probably due to an impurity. The emission spectra of K3[Co(CN)6] powder in the temperature range from room temperature to that of liquid hydrogen were observed by means of a modified Hitachi 203 fluorescence spectrophotometer. The broad emission band at room temperature showed some vibrational structures at low temperatures. The emission spectra of powders of [Cr(NH3)6](NO3)3 and [Cr(NH3)6][Co(CN)6] were also measured. The following results were obtained: i) Similar emission spectra, which seemed to originate from [Cr(NH3)6]3+, were observed with both complexes [Cr(NH3)6](NO3)3 and [Cr-(NH3)6][Co(CN)6] using mercury lines at 313, 365, and 435 nm for excitation, ii) With 254 nm excitation, such emission spectra as i) were not observed with [Cr(NH3)6](NO3)3, but the same emission spectra as in i) were observed with [Cr(NH3)6][Co(CN)6]. iii) The ratio of the emission intensities at 15000 cm−1 with 435 and 313 nm excitations was 1:0.25–0.30 for [Cr(NH3)6](NO3)3, but it was 1:1.5–1.7 for [Cr(NH3)6][Co(CN)6]. From these results, it was presumed that, in [Cr(NH3)6][Co(CN)6], there occurred an energy transfer from the complex anion to the complex cation. Furthermore, emission spectra were observed with [Cr(NH3)6](ClO4)3 and the equimolar mixture of complex salts [Cr(NH3)6](ClO4)3–K3[Co(CN)6] and [Cr(NH3)6](NO3)3–K3[Co(CN)6] for the purpose of confirming the energy transfer in [Cr(NH3)6][Co(CN)6]. The temperature dependence of the emission intensity was also discussed." @default.
• W2063255731 created "2016-06-24" @default.
• W2063255731 creator A5050403187 @default.
• W2063255731 date "1973-07-01" @default.
• W2063255731 modified "2023-09-27" @default.
• W2063255731 title "The Emission Spectra of Hexamminechromium(III) Hexacyanocobaltate(III), [Cr(NH₃)₆][Co(CN)₆]" @default.
• W2063255731 cites W1537068549 @default.
• W2063255731 cites W1580450181 @default.
• W2063255731 cites W1622717306 @default.
• W2063255731 cites W1639691876 @default.
• W2063255731 cites W1651771191 @default.
• W2063255731 cites W1666537872 @default.
• W2063255731 cites W1965018961 @default.
• W2063255731 cites W1968266456 @default.
• W2063255731 cites W1978739585 @default.
• W2063255731 cites W1980886040 @default.
• W2063255731 cites W1988570824 @default.
• W2063255731 cites W1995079027 @default.
• W2063255731 cites W1996990026 @default.
• W2063255731 cites W1999483288 @default.
• W2063255731 cites W2017333231 @default.
• W2063255731 cites W2041330814 @default.
• W2063255731 cites W2044354050 @default.
• W2063255731 cites W2045882451 @default.
• W2063255731 cites W2048353020 @default.
• W2063255731 cites W2054316210 @default.
• W2063255731 cites W2056762507 @default.
• W2063255731 cites W2061912279 @default.
• W2063255731 cites W2065611529 @default.
• W2063255731 cites W2080601193 @default.
• W2063255731 cites W2086209403 @default.
• W2063255731 cites W2088250316 @default.
• W2063255731 cites W2094674171 @default.
• W2063255731 cites W2099969506 @default.
• W2063255731 cites W2145147147 @default.
• W2063255731 cites W2328342884 @default.
• W2063255731 cites W2331954063 @default.
• W2063255731 cites W2334421933 @default.
• W2063255731 cites W3180519682 @default.
• W2063255731 cites W4243524177 @default.
• W2063255731 cites W4251919474 @default.
• W2063255731 cites W437953049 @default.
• W2063255731 doi "https://doi.org/10.1246/bcsj.46.2078" @default.
• W2063255731 hasPublicationYear "1973" @default.
• W2063255731 type Work @default.
• W2063255731 sameAs 2063255731 @default.
• W2063255731 citedByCount "7" @default.
• W2063255731 crossrefType "journal-article" @default.
• W2063255731 hasAuthorship W2063255731A5050403187 @default.
• W2063255731 hasBestOaLocation W20632557311 @default.
• W2063255731 hasConcept C113196181 @default.
• W2063255731 hasConcept C119824511 @default.
• W2063255731 hasConcept C121332964 @default.
• W2063255731 hasConcept C1276947 @default.
• W2063255731 hasConcept C153294291 @default.
• W2063255731 hasConcept C178790620 @default.
• W2063255731 hasConcept C185592680 @default.
• W2063255731 hasConcept C32891209 @default.
• W2063255731 hasConcept C39353612 @default.
• W2063255731 hasConcept C43617362 @default.
• W2063255731 hasConcept C4839761 @default.
• W2063255731 hasConcept C62520636 @default.
• W2063255731 hasConcept C71987851 @default.
• W2063255731 hasConcept C91881484 @default.
• W2063255731 hasConcept C96141758 @default.
• W2063255731 hasConceptScore W2063255731C113196181 @default.
• W2063255731 hasConceptScore W2063255731C119824511 @default.
• W2063255731 hasConceptScore W2063255731C121332964 @default.
• W2063255731 hasConceptScore W2063255731C1276947 @default.
• W2063255731 hasConceptScore W2063255731C153294291 @default.
• W2063255731 hasConceptScore W2063255731C178790620 @default.
• W2063255731 hasConceptScore W2063255731C185592680 @default.
• W2063255731 hasConceptScore W2063255731C32891209 @default.
• W2063255731 hasConceptScore W2063255731C39353612 @default.
• W2063255731 hasConceptScore W2063255731C43617362 @default.
• W2063255731 hasConceptScore W2063255731C4839761 @default.
• W2063255731 hasConceptScore W2063255731C62520636 @default.
• W2063255731 hasConceptScore W2063255731C71987851 @default.
• W2063255731 hasConceptScore W2063255731C91881484 @default.
• W2063255731 hasConceptScore W2063255731C96141758 @default.
• W2063255731 hasIssue "7" @default.
• W2063255731 hasLocation W20632557311 @default.
• W2063255731 hasOpenAccess W2063255731 @default.
• W2063255731 hasPrimaryLocation W20632557311 @default.
• W2063255731 hasRelatedWork W2013295596 @default.
• W2063255731 hasRelatedWork W2034011551 @default.
• W2063255731 hasRelatedWork W2035270385 @default.
• W2063255731 hasRelatedWork W2049446183 @default.
• W2063255731 hasRelatedWork W2064711102 @default.
• W2063255731 hasRelatedWork W2095113074 @default.
• W2063255731 hasRelatedWork W2286362193 @default.
• W2063255731 hasRelatedWork W2922204950 @default.
• W2063255731 hasRelatedWork W3165055104 @default.
• W2063255731 hasRelatedWork W4250571304 @default.
• W2063255731 hasVolume "46" @default.
• W2063255731 isParatext "false" @default.
• W2063255731 isRetracted "false" @default.
• W2063255731 magId "2063255731" @default.

• next