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• W2063271027 abstract "The reaction of [Fe(salen)](+) and {A(3)[Fe(CN)(6)]} (A = NEt(4), K), depending on the countercation A(+) and on the reaction solvent, led to [(NEt(4)){Fe(salen)}(2){Fe(CN)(6)}](n)(), 4, and [{Fe(salen)}(3){Fe(CN)(6)}(MeOH)(2)](n)().3nH(2)O, 5 [NEt(4) = tetraethylammonium cation, salen = N, N'-ethylenebis(salicylideneiminato) dianion], displaying a similar extended 2D structure. Complex 5 crystallizes in the monoclinic, space group P2(1)/n, a = 13.495(7) Å, b = 14.220(9) Å, c = 33.137(5) Å, beta = 96.74(2) degrees, and Z = 4. It assumes a two-dimensional network layer structure consisting of cyclic octanuclear [-Fe(h.s.)-NC-Fe(l.s.)-CN-](4) units with [Fe(salen)(MeOH)(2)](+) located between the interlayer as a countercation. Complex 4 exhibits a metamagnetic behavior with a field-induced transition from an antiferromagnetic to a ferromagnetic-like state and a Neel temperature of ca. 6 K." @default.
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• W2063271027 date "1998-05-02" @default.
• W2063271027 modified "2023-10-16" @default.
• W2063271027 title "The Synthesis and Characterization of Two-Dimensional Ferromagnetic Extended Structures Containing High-Spin (<i>S</i> = ⁵/₂) and Low-Spin (<i>S</i> = ¹/₂) Iron(III) Bridged by Cyanide Groups" @default.
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• W2063271027 doi "https://doi.org/10.1021/ic971544d" @default.
• W2063271027 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11670407" @default.
• W2063271027 hasPublicationYear "1998" @default.
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