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- W2063287705 abstract "Partial hydrolysis of Ti(III) and Ti(IV) chlorides in the presence of [PPh 4 ]Cl yielded a series of new complexes. Ti(III) chloride was obtained from reduction of TiCl 4 with 1 equiv. of HSnBu 3 . In CH 2 Cl 2 in the presence of TiCl 4 , the hydrolysis reaction led to the formation of a Ti(III)Ti(IV) mixed valent complex, namely, heptanuclear [PPh 4 ] 3 [Ti 7 Cl 19 O 3 ] ( 2 ) containing three face-sharing Ti 2 units and three edge-sharing Ti 2 units. When the reaction was conducted in acetone, only two Ti(III) complexes, namely, dinuclear edge-sharing [PPh 4 ] 2 [Ti 2 Cl 7 (OH)(H 2 O)(OCMe 2 )] ( 3 ) and mononuclear [TiCl 4 (H 2 O) 3 ] ( 4 ), were obtained. The hydrolysis products of TiCl 4 in the presence of [PPh 4 ]Cl include a one-dimensional polymeric compound, {[PPh 4 ][Ti 2 Cl 6 X]O} n (X Cl, OH) ( 5 ), and a mononuclear complex, [PPh 4 ][TiCl 5 (H 2 O)] ( 6 ). The simple addition product, [PPh 4 ] 2 [TiCl 6 ]] ( 7 ), was also isolated from this reaction Compounds 2–7 were all characterized by X-ray crystallography." @default.
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- W2063287705 date "1998-01-01" @default.
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- W2063287705 title "Partial hydrolysis of Ti(III) and Ti(IV) chlorides in the presence of [PPh4]Cl" @default.
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- W2063287705 doi "https://doi.org/10.1016/s0020-1693(97)05766-6" @default.
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