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- W2063294885 abstract "Abstract A report is given on the polymerization of 1,3-pentadiene by cobalt catalysts prepared from AlEt 2 Cl, Al 2 Et 3 Cl 3 or alkyl aluminum compounds containing AlOAl bonds. Depending on the aluminum compound used for preparing the catalyst and on the polymerization solvent (benzene, n -heptane, cis -2-butene), different polymers are obtained, i.e., crystalline polymers with a cis -1,4 syndiotactic structure, amorphous polymers composed of cis -1,4 and 1,2 units, and weakly crystalline polymers with a 1,2 syndiotactic structure. Characterization of the polymers is reported. The results are discussed in the light of the current theories on the mechanism of catalysis of stereospecific polymerization." @default.
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- W2063294885 date "1969-02-01" @default.
- W2063294885 modified "2023-09-27" @default.
- W2063294885 title "Polymerization of 1,3-pentadiene by cobalt catalysts. Synthesis of 1,2 and CIS-1,4 syndiotactic polypentadienes" @default.
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- W2063294885 doi "https://doi.org/10.1016/0014-3057(69)90097-4" @default.
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