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- W2063301001 endingPage "649" @default.
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- W2063301001 abstract "Some camphor-derived vinyl sulfones bearing an oxygen functionality at the allylic position have been synthesised and their nucleophilic epoxidation reactions under Meth-Cohn conditions have been explored. The γ-oxygenated camphor-derived vinyl sulfones underwent mildly diastereoselective nucleophilic epoxidation reactions, affording the derived sulfonyloxiranes in up to 5.8:1 dr. The diastereoselectivities observed were sensitive to the reaction conditions employed. In contrast, no stereoselectivity was observed in the nucleophilic epoxidation of the corresponding γ-oxygenated isobornyl vinyl sulfone. A tentative mechanism has been proposed to explain the origins of the diastereoselectivity." @default.
- W2063301001 created "2016-06-24" @default.
- W2063301001 creator A5003033801 @default.
- W2063301001 creator A5058847923 @default.
- W2063301001 date "2012-05-01" @default.
- W2063301001 modified "2023-09-27" @default.
- W2063301001 title "The diastereoselective Meth-Cohn epoxidation of camphor-derived vinyl sulfones" @default.
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- W2063301001 doi "https://doi.org/10.1016/j.tetasy.2012.04.014" @default.
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