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- W2063308178 abstract "The vibrational spectra of some 1:2 trimethylphosphine adducts of the group IV tetrahalides, which contain ligands in a trans configuration, are examined in detail using perdeutero-trimethylphosphine to facilitate the assignment of all metal–halogen and metal–phosphorus stretching modes. Preparation of SiCl 4• 2PMe 3 with a 1:1 mixture of P(CH 3 ) 3 and P(CD 3 ) 3 enables an almost unambiguous assignment of the spectrum of this adduct. Normal coordinate calculations for all adducts are reported." @default.
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- W2063308178 date "1973-08-15" @default.
- W2063308178 modified "2023-09-23" @default.
- W2063308178 title "1:2 Trimethylphosphine Complexes of the Group IV Tetrahalides, <i>trans</i>-MX<sub>4•</sub>2P(CH<sub>3</sub>)<sub>3</sub> and <i>trans</i>-MX<sub>4•</sub>2P(CD<sub>3</sub>)<sub>3</sub> (where M = Si, Ge, or Sn; X = Cl or Br); Assignment of Metal–Phosphorus modes" @default.
- W2063308178 doi "https://doi.org/10.1139/v73-405" @default.
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