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- W2063313588 abstract "The radical polymerization of 4-(4,5-diphenyl-1H-imidazol-yl)-phenyl acrylate (DPIPA) was carried out in N,N-dimethylformamide at 60 °C for 24 h by using 2,2′-azobis(isobutyronitrile) (5 mol%) as an initiator to give a poly(DPIPA) (1) as a homopolymer. Poly(DPIPA-co-MMA) (2) was obtained by the radical copolymerization of DPIPA with methyl methacrylate (MMA) in a good yield. Moreover, copolymeriztion parameters of DPIPA were evaluated by the copolymerization of MMA. The cross-linking reaction of the obtained 2 proceeded with K3[Fe(CN)6] and KOH. The resulting cross-linked poly(DPIPA-co-MMA) (3) was de-cross-linked by pressurization or visible light irradiation. Consequently, the thiol-capped de-cross-linked poly(DPIPA-co-MMA) (4) was obtained in a good yield." @default.
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- W2063313588 date "2013-07-01" @default.
- W2063313588 modified "2023-10-18" @default.
- W2063313588 title "Synthesis and properties of de-cross-linkable acrylate polymers based on hexaarylbiimidazole" @default.
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- W2063313588 doi "https://doi.org/10.1016/j.polymer.2013.05.066" @default.
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