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- W2063326872 abstract "The thermodynamic constants of the hindered rotation around the S2CNR2 bond of N,N,N′,N′-tetraethylthiuram disulfide and its complexes with Zn, Cd and Hg(II) halides have been obtained by NMR. It is shown that the effect of the solvent on the rotation rate is small. At low temperatures the NMR patterns reveal the existence of a second process that interchanges inequivalent ethyl groups. This process is due to the nonequivalence of the ligand sulfur atoms as can be seen from the crystallographic structure of HgI2 (Me4tds). The thermodynamic constants of the interconversion between these two inequivalent configurations are also presented." @default.
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- W2063326872 date "2010-09-02" @default.
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- W2063326872 title "A NMR study of N,N,N′,N′-tetraethylthiuram disulfide and its complexes with ZnI2, CdI2 and HgI2" @default.
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- W2063326872 doi "https://doi.org/10.1002/recl.19730920608" @default.
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