FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2063358416> ?p ?o ?g. }

• W2063358416 endingPage "7757" @default.
• W2063358416 startingPage "7750" @default.
• W2063358416 abstract "Here, we study the nature of metal–metal bonding in the ThCr2Si2 structure type by probing the rate-limiting steps in the oxidative deintercalation of KNi2Se2. For low extents of oxidation, alkali ions are removed exclusively to form K1–xNi2Se2. For greater extents of oxidation, the rate of the reaction decreases dramatically, concomitant with the extraction of both potassium and nickel to form K1–xNi2–ySe2. The appreciable mobility of transition metal ions is unexpected, but illustrates the relative energy scales of different defects in the ThCr2Si2 structure type. Furthermore, the fully oxidized compounds, K0.25Ni1.5Se2, spontaneously convert from the tetrahedral [NiSe4]-containing ThCr2Si2 structure to a vacancy-ordered NiAs structure with [NiSe6] octahedra. From analysis of the atom positions and kinetic data, we have determined that this transformation occurs by a continuous, low-energy pathway via subtle displacements of Ni atoms and buckling of the Se sublattice. These results have profound implications for our understanding of the stability, mobility, and reactivity of ions in materials." @default.
• W2063358416 created "2016-06-24" @default.
• W2063358416 creator A5040550673 @default.
• W2063358416 creator A5080034867 @default.
• W2063358416 date "2012-04-30" @default.
• W2063358416 modified "2023-10-17" @default.
• W2063358416 title "Bonding, Ion Mobility, and Rate-Limiting Steps in Deintercalation Reactions with ThCr₂Si₂-type KNi₂Se₂" @default.
• W2063358416 cites W137723166 @default.
• W2063358416 cites W1480537269 @default.
• W2063358416 cites W1602728087 @default.
• W2063358416 cites W1611068772 @default.
• W2063358416 cites W1647415306 @default.
• W2063358416 cites W1949231392 @default.
• W2063358416 cites W1970586707 @default.
• W2063358416 cites W1991464345 @default.
• W2063358416 cites W1993482243 @default.
• W2063358416 cites W2006318126 @default.
• W2063358416 cites W2011871270 @default.
• W2063358416 cites W2025751043 @default.
• W2063358416 cites W2031975877 @default.
• W2063358416 cites W2034467213 @default.
• W2063358416 cites W2037015363 @default.
• W2063358416 cites W2042653297 @default.
• W2063358416 cites W2048297391 @default.
• W2063358416 cites W2053876908 @default.
• W2063358416 cites W2056707791 @default.
• W2063358416 cites W2057905482 @default.
• W2063358416 cites W2058466699 @default.
• W2063358416 cites W2059009017 @default.
• W2063358416 cites W2060142904 @default.
• W2063358416 cites W2067691337 @default.
• W2063358416 cites W2070059498 @default.
• W2063358416 cites W2070835228 @default.
• W2063358416 cites W2076938722 @default.
• W2063358416 cites W2084828962 @default.
• W2063358416 cites W2091022750 @default.
• W2063358416 cites W2132216432 @default.
• W2063358416 cites W2135156383 @default.
• W2063358416 cites W2140271862 @default.
• W2063358416 cites W2171962907 @default.
• W2063358416 cites W2313730682 @default.
• W2063358416 cites W2766978321 @default.
• W2063358416 cites W2953349182 @default.
• W2063358416 cites W3106376237 @default.
• W2063358416 cites W4239300717 @default.
• W2063358416 cites W4253081985 @default.
• W2063358416 doi "https://doi.org/10.1021/ja212012k" @default.
• W2063358416 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/22530571" @default.
• W2063358416 hasPublicationYear "2012" @default.
• W2063358416 type Work @default.
• W2063358416 sameAs 2063358416 @default.
• W2063358416 citedByCount "48" @default.
• W2063358416 countsByYear W20633584162012 @default.
• W2063358416 countsByYear W20633584162013 @default.
• W2063358416 countsByYear W20633584162014 @default.
• W2063358416 countsByYear W20633584162015 @default.
• W2063358416 countsByYear W20633584162016 @default.
• W2063358416 countsByYear W20633584162017 @default.
• W2063358416 countsByYear W20633584162018 @default.
• W2063358416 countsByYear W20633584162019 @default.
• W2063358416 countsByYear W20633584162020 @default.
• W2063358416 countsByYear W20633584162021 @default.
• W2063358416 countsByYear W20633584162022 @default.
• W2063358416 countsByYear W20633584162023 @default.
• W2063358416 crossrefType "journal-article" @default.
• W2063358416 hasAuthorship W2063358416A5040550673 @default.
• W2063358416 hasAuthorship W2063358416A5080034867 @default.
• W2063358416 hasConcept C106773901 @default.
• W2063358416 hasConcept C114221277 @default.
• W2063358416 hasConcept C115624301 @default.
• W2063358416 hasConcept C121332964 @default.
• W2063358416 hasConcept C127413603 @default.
• W2063358416 hasConcept C135889238 @default.
• W2063358416 hasConcept C142724271 @default.
• W2063358416 hasConcept C145148216 @default.
• W2063358416 hasConcept C147597530 @default.
• W2063358416 hasConcept C161790260 @default.
• W2063358416 hasConcept C178790620 @default.
• W2063358416 hasConcept C179104552 @default.
• W2063358416 hasConcept C185592680 @default.
• W2063358416 hasConcept C188198153 @default.
• W2063358416 hasConcept C198091228 @default.
• W2063358416 hasConcept C198819137 @default.
• W2063358416 hasConcept C204787440 @default.
• W2063358416 hasConcept C2776910235 @default.
• W2063358416 hasConcept C504270822 @default.
• W2063358416 hasConcept C544153396 @default.
• W2063358416 hasConcept C62520636 @default.
• W2063358416 hasConcept C71924100 @default.
• W2063358416 hasConcept C78519656 @default.
• W2063358416 hasConcept C8010536 @default.
• W2063358416 hasConceptScore W2063358416C106773901 @default.
• W2063358416 hasConceptScore W2063358416C114221277 @default.
• W2063358416 hasConceptScore W2063358416C115624301 @default.
• W2063358416 hasConceptScore W2063358416C121332964 @default.
• W2063358416 hasConceptScore W2063358416C127413603 @default.
• W2063358416 hasConceptScore W2063358416C135889238 @default.
• W2063358416 hasConceptScore W2063358416C142724271 @default.

• next