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- W2063362018 abstract "With benzophenone (Ph2CO) and its-Cl- and 4-Br-derivatives, antimony trichloride and tribromide form solid 1:1 molecular complexes; their i.r. spectra show that the metal atom is not coordinated to the CO group. 1:1 complexes too are formed in dilute dichloromethane (DCM) solutions; their equilibrium constants, determined from their charge transger bands by the Benesi—Hildebrand method, decrease in the order Ph2CO > 4-BrPh2CO > 4-ClPh2CO and SbCl3 > SbBr3 in agreement with the decreasing dipole moments both of the donors and of the acceptors. The ligand 4-NH2Ph2CO forms two solid, yellow and red, complexes with SbX3:ligand ratios: 2:1 and 1:2 fpr SbCl3, 2:3 (:5DCM) and 1:1 for SbBr3, 2:1 and 1:1 for SbI3, respectively. The yellow complex becomes spontaneously red in DCM solution and, for SbCl3, also in the solid state. The i.r. spectra show that also in these complexes the metal atom is not coordinated to the CO group and in the red 1:2 SbCl3− and in the yellow 2:1 SbI3-complex not even to the NH2 group of the ligand; in the other 4-NH2Ph2CO-complexes the ligand seems to be N-bonded to the metal." @default.
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- W2063362018 date "1976-01-01" @default.
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- W2063362018 title "Molecular complexes of antimony trihalides with benzophenone, 4-Cl-, 4-Br- and 4-NH2-benzophenone." @default.
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- W2063362018 doi "https://doi.org/10.1016/0584-8539(76)80133-x" @default.
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