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- W2063392175 abstract "Hydrolysis of 3β-5-diacetoxy-5β-cholestan-6-one oxime (1) gave seven products which, in addition to 3β-acetoxy- and (6E)-3β-hydroxy-5-methoxy-5α-cholestan-6-one oxime (3 and 4), are identified as the dimeric steroids (6E,6′E)-6-(6′-hydroxyimino-5′α-cholestan-5′-yl-oximino)cholestanes 6–10. On the other hand, the 3α epimer 3α,5-diacetoxy-5β-cholestan-6-one oxime (2) afforded the monomeric (6E)-3α-hydroxy-5-methoxy-5α-cholestan-6-one oxime (5) and (6E)-3α-hydroxy-4-cholesten-6-one oxime (11) only. All new compounds are characterized by NMR and MS methods. The CD spectra of 1–12 are documented." @default.
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- W2063392175 date "1992-07-24" @default.
- W2063392175 modified "2023-10-13" @default.
- W2063392175 title "Synthesis and Spectroscopic Characterization of Dimeric Steroidal Oximes" @default.
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- W2063392175 doi "https://doi.org/10.1002/jlac.1992199201120" @default.
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