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• W2063432108 abstract "C–S bond cleavage in pyridylmethylthioether systems promoted by oxorhenium(V) ion has been established performing the reaction of 1,2-bis(2-pyridylmethylthio)ethane(BPT1), 1,3-bis(2-pyridyl-methylthio)propane(BPT2) and 3,4-bis(2-pyridylmethylthio)-5-methyltoluene (BPT3) with Bu4N[ReOCl4] in dry alcoholoic medium. In case of BPT1 and BPT2, new 2-(2-pyridylmethylthio)ethane-1-thiol (L1H) and 3-(2-pyridylmethylthio)propane-1-thiol (L2H) ligand, respectively were formed in situ through cleavage of one C–S(thioether) bond, resulting in the neutral oxorhenium(V) complexes of formulation [ReO(L1)Cl2] (1a) and [ReO(L2)Cl2] (1b); where as in case of BPT3, binary oxorhenium(V) complex of 3,4-dimercapto-toluene ligand (L3H2), formulated as Bu4N[ReO(L3)2] (1c) through cleavage of two C–S(thioether) bonds. The presence of picolinic acid, as by-product in the filtrates of the C–S bond cleavage reactions in dry alcohol, was detected by treatment of copper(II) salts and GC–MS techniques. But in hydrated alcoholic medium no C–S bond cleavage induced by ReO(V) ion occurred in any of the BPT systems rather the conversion of ReO(V) into perrhenate salt was observed; this reaction mixture, in turn on reaction with copper(II) nitrate trihydrate salt, produce [Cu(BPT)Cl]ReO4 (2) type complexes. The solid-state structures of complexes 1a and 2a were established by X-ray crystallography." @default.
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• W2063432108 date "2009-11-01" @default.
• W2063432108 modified "2023-10-17" @default.
• W2063432108 title "C–S bond cleavage in pyridylmethylthioether systems promoted by oxorhenium(V) ion" @default.
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• W2063432108 doi "https://doi.org/10.1016/j.inoche.2009.08.035" @default.
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