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- W2063447029 abstract "Abstract The infrared multiphoton dissociation (IRMPD) of pure SiF 4 and in mixtures with different gases was studied using a tunable CO 2 TEA laser. The initial dissociation step of the IRMPD of SiF 4 was found to be the decomposition into SiF 3 and F. The gas phase reactions of trifluorosilyl, SiF 3 , with F and H 2 was investigated. A kinetic scheme was proposed to explain the experimental results. The set of coupled differential equations associated to this scheme was numerically solved. The rate constants of the SiF 3 +F→SiF 4 and SiF 3 +H 2 →SiF 3 H+H reactions were determined." @default.
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- W2063447029 date "2004-07-01" @default.
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- W2063447029 title "Infrared multiphoton dissociation of SiF4: gas phase reactions of SiF3 with F and H2" @default.
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- W2063447029 doi "https://doi.org/10.1016/j.jphotochem.2004.03.019" @default.
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