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- W2063456425 abstract "The structure of Al2(CD3)6 has been determined at 4.5 K by powder neutron diffraction. The molecule crystallizes in space group C2/c. Salient bond distances and angles are as follows: r(Al−Cb) = 2.145(7)/2.146(8) Å, r(Al−Ct) = 1.945(6)/1.926(5) Å, r(Al···Al) = 2.700(10) Å, r(C−D) = 1.061(4)−1.118(5) Å; ∠Cb−Al−Cb = 102.0(3)°, ∠Ct−Al−Ct = 125.8(3)°, ∠Cb−Al−Ct = 108.8(4)°, ∠D−C−D = 99.0(4)−111.6(5)°. The bridging CD3 groups adopt a staggered conformation with respect to each other in a molecule with C2h symmetry, and there is no evidence in the structure for the involvement of the C−D bonds in Al−CD3−Al bridge bonding. Variable-temperature studies show the lattice constant b to exhibit unusual behavior, initially decreasing with increasing temperature. This phenomenon is interpreted in terms of increasing thermal motion of the molecule with increasing temperature." @default.
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- W2063456425 date "2000-09-21" @default.
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- W2063456425 title "Structure of the Trimethylaluminum Dimer As Determined by Powder Neutron Diffraction at Low Temperature" @default.
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- W2063456425 doi "https://doi.org/10.1021/om0004794" @default.
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