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- W2063479546 abstract "Cationic porphyrins such as tetrakis(N-alkylpyridyl)porphyrins2,3, tetrakis(N-methylpyridyloxy)-phthalocyanines5 or tetrakis(N-alkylpyrido)tetraazaporphyrin6,7 in either metal-free or zinc-containing forms are incorporated readily into AlPO4-5 molecular sieves by crystallization inclusion. The dye molecules, which are much larger than the channel diameter of the molecular sieve, are encapsulated in mesopores as revealed from adsorption isotherms. The chromophores are predominantly present as monomers as gleaned from u.v./vis spectra. The surprisingly strongly enhanced photostability, in comparison to the photostability in solution, is a direct proof for the encaged state of the porphyrins and a fundamental prerequisite for any potential application under visible light conditions." @default.
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- W2063479546 date "1995-08-01" @default.
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- W2063479546 title "Preparation and photostability of porphyrins incorporated into AlPO4-5 molecular sieves by crystallization inclusion" @default.
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- W2063479546 doi "https://doi.org/10.1016/0144-2449(94)00066-2" @default.
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