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- W2063506870 abstract "Abstract Examination of a series of concentrated ZnCl2HClH2O solutions with chloride/zinc stoichiometries ranging from 2:1 to 6:1 and with the mole fraction of Zn2+ being 0·015 in each solution have been examined by X-ray diffraction. The mean coordination of Zn2+ in each solution is pseudotetrahedral with the ZnCl and ZnO contact distances being 2·30 and 2·05 A, respectively. The average number of chlorides tightly bonded to Zn2+ is, as expected, significantly related to the chloride/zinc and/or the chloride/water stoichiometries. The formation constant for tetrachlorozincate (II) in these solutions is ca. 80 M−2 if it is assumed that tetrachlorozincate(II) and/or dichlorodiaquozinc(II) are the principal species in each of these solutions." @default.
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- W2063506870 date "1973-03-01" @default.
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- W2063506870 title "Solute species and equilibria in concentrated zinc chloride/hydrochloric acid solutions" @default.
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- W2063506870 doi "https://doi.org/10.1016/0022-1902(73)80455-5" @default.
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